Stacking disorder in ice I

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Stacking disorder in ice I.

Traditionally, ice I was considered to exist in two well-defined crystalline forms at ambient pressure: stable hexagonal ice (ice Ih) and metastable cubic ice (ice Ic). However, it is becoming increasingly evident that what has been called cubic ice in the past does not have a structure consistent with the cubic crystal system. Instead, it is a stacking-disordered material containing cubic sequ...

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Extent and relevance of stacking disorder in "ice I(c)".

A solid water phase commonly known as "cubic ice" or "ice I(c)" is frequently encountered in various transitions between the solid, liquid, and gaseous phases of the water substance. It may form, e.g., by water freezing or vapor deposition in the Earth's atmosphere or in extraterrestrial environments, and plays a central role in various cryopreservation techniques; its formation is observed ove...

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Communication: Thermodynamics of stacking disorder in ice nuclei.

A simple Ising-like model for the stacking thermodynamics of ice 1 is constructed for nuclei in supercooled water, and combined with classical nucleation theory. For relative stabilities of cubic and hexagonal ice I within the range of experimental estimates, this predicts critical nuclei are stacking disordered at strong sub-cooling, consistent with recent experiments. At higher temperatures n...

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Mapping ice-shelf flow with interferometric synthetic aperture radar stacking

Interferometric synthetic aperture radar (InSAR) observations of ice-shelf flow contain ocean-tide and atmospheric-pressure signals. A model-based correction can be applied, but this method is limited by its dependency upon model accuracy, which in remote regions can be uncertain. Here we describe a method to determine two-dimensional ice-shelf flow vectors independently of model predictions of...

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ژورنال

عنوان ژورنال: Physical Chemistry Chemical Physics

سال: 2015

ISSN: 1463-9076,1463-9084

DOI: 10.1039/c4cp02893g